中国农业科技导报 ›› 2017, Vol. 19 ›› Issue (1): 125-130.DOI: 10.13304/j.nykjdb.2016.209

• 资源环境 生物药物 生物质转化 • 上一篇    下一篇

初烤烟叶有机酸对主流烟气有害成分释放量的影响

李燕1,褚智国2,田海英3,郝辉3,宋金勇3,周浩3,李怀奇3,刘鹏飞1,赵铭钦1*   

  1. 1.河南农业大学烟草学院, 郑州 450002; 2.山东中烟工业有限责任公司, 山东 青岛 266101;
    3.河南中烟工业有限责任公司技术中心, 郑州 450000
  • 收稿日期:2016-04-11 出版日期:2017-01-15 发布日期:2016-06-14
  • 通讯作者: 赵铭钦,教授,博士,主要从事烟草质量评价、烟草化学与香精香料等研究。E-mail:zhaomingqin@126.com
  • 作者简介:李燕,硕士研究生,研究方向为烟草化学与烟气成分关系研究。E-mail:liyan91513@126.com。
  • 基金资助:
    中国烟草总公司重大专项(110201101001TS-01);上海烟草集团有限责任公司项目(szbcw201201150);浙江中烟工业公司项目(ZJZY201205)资助。

Influences of Organic Acids on Deliveries of Harmful Components in Mainstream Smoke from Flue-curd Tobacco Leaf

LI Yan1, CHU Zhiguo2, TIAN Haiying3, HAO Hui3, SONG Jinyong3, ZHOU Hao3, LI Huaiqi3, LIU Pengfei1, ZHAO Mingqin1*   

  1. 1.College of Tobacco Science, Henan Agricultural University, Zhengzhou 450002;
    2.Shandong Branch of China Tobacco Industry Corporation Ltd., Shandong Qingdao 266101;3.Technology Center, Henan Branch of China Tobacco Industry Corporation Ltd., Zhengzhou 450000, China
  • Received:2016-04-11 Online:2017-01-15 Published:2016-06-14

摘要: 为了降低卷烟危害性,全面系统地阐述初烤烟叶中化学成分对卷烟主流烟气有害成分释放量的影响,以2014年浓香型主产区烤烟样品为试验材料,采用因子分析和灰色关联法对初烤烟叶有机酸对主流烟气中有害成分释放量的影响进行研究。结果表明:因子分析共提取出草酸、富马酸、苹果酸、柠檬酸、丙二酸、棕榈酸、油酸、十八酸8种代表性有机酸。灰色关联度分析显示草酸、丙二酸、富马酸、苹果酸、柠檬酸5种非挥发性有机酸对烟气7种有害成分(CO、HCN、NNK、NH3、BP、苯酚和巴豆醛)及焦油释放量和卷烟危害性指数的关联度均较高,尤其是草酸对烟气有害成分的危害性指数有较高的关联度;而棕榈酸、油酸、十八酸等高级脂肪酸对烟气7种有害成分及焦油释放量和卷烟危害性指数的关联度相对较低。总体来说,初烤烟叶中有机酸成分中非挥发性有机酸对卷烟主流烟气有害成分的产生有较大影响,而高级脂肪酸对其影响相对较小。

关键词: 烤烟, 有机酸, 烟气有害成分, 因子分析, 灰色关联度分析

Abstract: In order to reduce the harmful components in cigarette smoke, and systematically describe the effects of tobacco leaf chemical components on burst size of harmful  cigarette mainstream smoke, this paper took the flue-cured tobacco samples from the main aromatic tobacco producing areas in 2014 as test material, and carried out studies by factor analysis and grey correlation method. The results showed that 8 representative organic acids were extracted using factor analysis, including oxalic acid, fumaric acid, malic acid, citric acid, malonic acid, hexadecanoic acid, oleic acid and stearic acid. The grey correlation analysis showed that the correlation degree of 5 non-volatile organic acids(oxalic acid, malonic acid, fumaric acid, malic acid and citric acid) and 7 harmful components (CO, HCN, NNK, NH3, B\[a\]P, phenol and crotonaldehyde), and tar content, cigarette hazard index were higher, especially the correlation of oxalic acid on harmful components had high correlation index. While that of the higher fatty acids, such as palmitic acid, oleic acid, stearic acid on cigarette hazard index of 7  harmful components and tar were relatively lower. In general, the non-volatile organic acids in flue-cured tobacco had great influences on the harmful components of cigarette mainstream smoke, while the higher fatty acids had relatively smaller effect.

Key words: flue-cured tobacco, organic acid, harmful components of cigarette smoke, factor analysis, grey correlation analysis