天然高分子絮凝剂的制备及应用研究

doi:10.13304/j.nykjdb.2022.0419

摘要/Abstract

摘要：

天然高分子絮凝剂是当前研究热点。详细介绍了天然高分子絮凝剂的作用机理、种类、特点，综述了其制备技术进展及应用现状，特别是在水处理领域的应用情况。并针对新型絮凝剂目前存在的问题，展望了未来的研究重点和发展方向，为新型絮凝剂的深入研究以及实际应用提供参考。

关键词: 天然高分子絮凝剂, 絮凝机理, 提取, 改性, 应用现状

Abstract:

Natural polymer flocculant is the focus of current research. The mechanism， type and characteristics of natural polymer flocculants were detailed introducted， and the progress of preparation technology， the application status of natural polymer flocculants， especially their application in the field of water treatment were summarized. In view of the current problems of the new flocculant， the future research focus and development direction were looked forward， which provided a reference for the in-depth research and practical application of the new flocculant.

Key words: natural polymer flocculant, flocculation mechanism, extraction, modification, application status

中图分类号:

O636.9

蔡阳扬, 陶秀萍, 李同, 尚斌, 宋建超, 刘璐. 天然高分子絮凝剂的制备及应用研究[J]. 中国农业科技导报, 2023, 25(10): 165-172.

Yangyang CAI, Xiuping TAO, Tong LI, Bin SHANG, Jianchao SONG, Lu LIU. Preparation and Application of Natural Polymer Flocculants[J]. Journal of Agricultural Science and Technology, 2023, 25(10): 165-172.

参考文献 44

1	ZHANG X, GRAHAM N, XU L, et al.. The influence of small organic molecules on coagulation from the perspective of hydrolysis competition and crystallization [J]. Environ. Sci. Technol., 2021, 55(11):7456-7465.
2	SUN Y J, SUN W Q, et al.. Characterization and flocculation evaluation of a novel carboxylated chitosan modified flocculant by UV initiated polymerization [J]. Carbohydr. Polym., 2019, 208:213-220.
3	CHEN F M, WANG Y L, JIA R B, et al.. Characteristics and mechanism of chitosan in flocculation for water coagulation in the Yellow River diversion reservoir [J/OL]. J. Water Process. Eng., 2020, 34:101191 [2022-04-10]. .
4	刘伟,马金菊,姚新鼎,等.淀粉絮凝剂在水处理中的研究进展[J].化工环保,2018,38(2):141-147.
	LIU W, MA J J, YAO X D, et al.. Research progresses on starch flocculants for water treatment [J]. Environ. Prot. Chem. Ind., 2018, 38(2):141-147.
5	WU Y, JIANG J, SUN Q, et al.. Efficient removal of both positively and negatively charged colloidal contaminants using amphoteric starch-based flocculants synthesized by low-pressure UV initiation [J/OL]. Sep. Purif. Technol., 2022, 282: 120120 [2022-04-10]. .
6	孙英娟,杨永利.淀粉接枝丙烯酰胺絮凝剂在煤泥水处理中的应用[J].中国煤炭,2017,43(2):86-91.
	SUN Y J, YANG Y L. Application of polyacrylamide-grafted starch copolymer flocculant in coal slurry wastewater treatment [J]. China Coal, 2017, 43(2):86-91.
7	HUANG M, LIU Z Z, LI A M, et al.. Dual functionality of a graft starch flocculant: flocculation and antibacterial performance [J]. J. Environ. Manage., 2017, 196:63-71.
8	袁媛,荣雅利,杨丰,等.甲壳素/壳聚糖的分离提取方法及在食品工业中的应用研究现状[J].食品与发酵工业,2020,46(18):252-258.
	YUAN Y, RONG Y L, YANG F, et al.. The separation and extraction methods of chitin/chitosan and its application in food industry [J]. Food. Ferment. Ind., 2020, 46(18):252-258.
9	孙岗,冯颖,张建伟.强化壳聚糖絮凝性能研究进展[J].应用化工,2020,49(4):974-978, 985.
	SUN G, FENG Y, ZHANG J W. Research progress on strengthening the flocculation performance of chitosan [J]. Appl. Chem. Ind., 2020, 49(4):974-978, 985.
10	白立军.壳聚糖衍生物絮凝剂对丁烯醛废水中COD的去除研究[J].工业水处理,2020,40(9):65-69.
	BAI L J. COD removal in crotonaldehyde wastewater by chitosan derivative flocculant [J]. Ind. Water Treat., 2020, 40(9):65-69.
11	高树生,张文柯,丁秋炜,等.改性壳聚糖类絮凝剂的合成及性能评价[J].工业水处理,2019,39(9):91-93, 107.
	GAO S S, ZHANG W K, DING Q W, et al.. Synthesis and evaluation of modified chitosan flocculant [J]. Ind. Water Treat., 2019, 39(9):91-93, 107.
12	岳弈君.羧甲基纤维素接枝聚脒絮凝剂的合成、表征及在废水处理中的应用[D].西安:西北大学,2019.
	YUE Y J. Carboxymethylcellulose grafted polyamidine flocculant: synthesis, characterization and flocculation performance test [D]. Xi’an: Northwest University, 2019.
13	黄文秀. NaOH/Urea均一体系中制备微晶纤维素基季铵型絮凝剂及其应用[D].济南:齐鲁工业大学,2019.
	HUANG W X. Preparation of microcrystalline cellulose-based quaternary ammonium flocculant in NaOH/Urea uniform system and application [D]. Jinan: Qilu University of Technology, 2019.
14	陈腾飞,郭延柱,初婷婷,等.阳离子型木质素基絮凝剂的半干法合成及在造纸废水处理中的应用[J].中国造纸学报,2019,34(4):27-33.
	CHEN T F, GUO Y Z, CHU T T, et al.. Hemi-dry synthesis of cationic lignin-based flocculants and its application in papermaking wastewater treatment [J]. Trans. China Pulp Pap., 2019, 34(4):27-33.
15	YIN H J, LIU L H, WANG X, et al.. A novel flocculant prepared by lignin nanoparticles-gelatin complex from switch-grass for the capture of Staphylococcus aureus and Escherichia coli [J]. Colloids Surf. A Physicochem. Eng. Asp., 2018, 545:51-59.
16	凌新龙,阳辰峰,宁军霞.纤维素的改性及应用研究进展[J].纺织科学与工程学报,2020,37(3):60-85.
	LING X L, YANG C F, NING J X. Research progress in modification of cellulose and application [J]. J. Tex. Sci. Eng., 2020, 37(3):60-85.
17	郑续,王慧梅,刘忠,等.小麦秸秆的蒸汽爆破及其产物表征[J].天津科技大学学报,2020,35(4):26-30.
	ZHENG X, WANG H M, LIU Z, et al.. Steam explosion of wheat straw and characterization of its products [J]. J. Tianjin Univ. Sci. Technol., 2020, 35(4):26-30.
18	冯志强,王彬莹,章泳川,等.微波辅助提取柚皮纤维素及结构分析[J].粮食与油脂,2022,35(4):124-128.
	FENG Z Q, WANG B Y, ZHANG Y C, et al.. Microwave-assisted extraction and structural analysis of cellulose from pomelo peel [J]. Cereals Oils, 2022, 35(4):124-128.
19	蓝尉冰,徐开平,韩鑫,等.微波辅助法制备南美白对虾甲壳素的工艺优化[J].食品工业科技,2018,39(20):135-140.
	LAN W B, XU K P, HAN X, et al.. Optimization of preparation process of chitin from penaeus vannamei by microwave assisted method [J]. Sci. Technol. Food Ind., 2018, 39(20):135-140.
20	李敏,张倩芳,栗红瑜,等.基于不同提取方法对藜麦淀粉性质的比较[J].食品研究与开发,2022,43(1):17-24.
	LI M, ZHANG Q F, LI H Y, et al.. Comparison between quinoa starches isolated using different extraction methods [J]. Food Res. Dev., 2022, 43(1):17-24.
21	周瑾琨,尹志慧,赵玮.玉米皮纤维素提取工艺优化及结构表征[J].食品工业科技,2019,40(5):207-212.
	ZHOU J K, YIN Z H, ZHAO W. Optimization of extraction technique and structure characterization of cellulose from corn bran [J]. Sci. Technol. Food Ind., 2019, 40(5):207-212.
22	张宁,辛向东,张月月,等.桑枝纤维素的低共熔溶剂法提取及其结构表征[J].蚕业科学,2021,47(5):451-458.
	ZHANG N, XIN X D, ZHANG Y Y, et al.. Extraction of cellulose from mulberry branch by deep eutecitic solvent and its structure characterization [J]. Sci. Seric., 2021, 47(5):451-458.
23	刘涛,张铁鹏,刘宁,等‍.水提法提取香蕉皮淀粉的工艺研究[J].中国调味品,2021,46(6):23-28, 36.
	LIU T, ZHANG T P, LIU N, et al.. Study on the extraction technology of starch from banana peel by water extraction method [J]. China Condiment, 2021, 46(6):23-28, 36.
24	王娜,肖云峰,钱新宇,等.莜麦淀粉的提取工艺优化及其相关特性研究[J].中国粮油学报,2020,35(9):47-53.
	WANG N, XIAO Y F, QIAN X Y, et al.. Optimization of extraction technology and characteristics of naked oats starch [J]. J. Chin. Cereals Oils Assoc., 2020, 35(9):47-53.
25	王蒙,李澜鹏,张全,等.生物法制备甲壳素/壳聚糖的研究进展[J].生物技术通报,2019,35(4):213-222.
	WANG M, LI L P, ZHANG Q, et al.. Research progress on the bio-production of chitin and chitosan [J]. Biotechnol. Bull., 2019, 35(4):213-222.
26	张巧,李永成.南美白对虾虾壳甲壳素的提取工艺及结构分析[J].食品科技,2020,45(4):187-192.
	ZHANG Q, LI Y C. Preparation and structural characterization of chitin from shrimp shell of Penaeus vannamei [J]. Food Sci. Technol., 2020, 45(4): 187-192.
27	孙正秋,牛梅红‍.高沸醇溶剂法提取丝瓜络中的木质素[J].大连工业大学学报,2020,39(4):270-275.
	SUN Z Q, NIU M H. Extraction of lignin from loofah using organosolv method with high boiling alcohol [J]. J. Dalian Polytech. Univ., 2020, 39(4):270-275.
28	苗长林,李惠文,吕鹏梅,等.离子液体提取木质素及环氧树脂的合成[J].太阳能学报,2021,42(1):371-378.
	MIAO C L, LI H W, LYU P M, et al.. Ionic liquid extracted of lignin and synthesis of epoxy resin [J]. Acta Energ. Sol. Sin., 2021, 42(1):371-378.
29	李蕴,张秀丽.纤维素酶法提取黑豆中可溶性膳食纤维的工艺研究[J].粮食与油脂,2020,33(7):79-82.
	LI Y, ZHANG X L. Study on the extraction process of soluble dietary fiber from black soybean by cellulase method [J]. Cereals Oils, 2020, 33(7):79-82.
30	蓝绪悦,王玲,杜沁岭,等.酶辅助碱法提取龙眼核淀粉的结构与理化性质研究[J].食品工业科技,2022,43(13):42-48.
	LAN X Y, WANG L, DU Q L, et al.. Structural and physicochemical properties of longan kernel starch by enzyme-assisted alkali extraction [J]. Sci. Technol. Food Ind., 2022, 43(13):42-48.
31	刘信旭,曾辉,时鹏,等.菌酶联合法提取松墨天牛甲壳素[J].西北林学院学报,2019,34(2):179-186.
	LIU X X, ZENG H, SHI P, et al.. Bacterium-protease combined method to extract chitin from Monochamus alternatus [J]. J. Northwest For. Univ., 2019, 34(2): 179-186.
32	张旺. 天然高分子接枝阳离子型絮凝剂的制备及絮凝性能研究[D].西安:西北大学,2021.
	ZHANG W. Preparation and flocculation performance of natural polymer grafted cationic flocculant [D]. Xi’an: Northwest University, 2021.
33	EL-NAGGAR M E, SAMHAN F A, SALAMA A, et al.. Cationic starch: safe and economic harvesting flocculant for microalgal biomass and inhibiting E. coli growth [J]. Int. J. Biol. Macromol., 2018, 116:1296-1303.
34	WANG Y, HOU T, YANG Z, et al.. Nitrogen-free cationic starch flocculants: flocculation performance, antibacterial ability, and uf membrane fouling control [J]. ACS Appl. Biol. Mater., 2020, 3(5):2910-2919.
35	YUSOFF M S, AZIZ H A, ZAMRI M F M A, et al.. Floc behavior and removal mechanisms of cross-linked Durio zibethinus seed starch as a natural flocculant for landfill leachate coagulation-flocculation treatment [J]. Waste Manage., 2018, 74:362-372.
36	宫晨,郭雅妮,杨卓,等.交联改性对木薯淀粉絮凝剂絮凝性能的影响[J].化学工程师,2021,35(7):14-18, 25.
	GONG C, GUO Y N, YANG Z, et al.. Effect of cross-linking modification on the flocculation performance of cassava starch flocculant [J]. Chem. Eng., 2021, 35(7):14-18, 25.
37	郑洁.天然有机高分子絮凝剂合成机理及其对难生物降解有机污染物的强化去除研究[D].重庆:重庆工商大学,2021.
	ZHENG J. Synthesis mechanisms of natural or ganic polymer flocculants and its application in removal of refractory organic pollutants [D]. Chongqing: Chongqing Technology and Business University, 2021.
38	郑怀礼,钟政,邹宏,等.磁性阳离子型壳聚糖絮凝剂去除Cr(Ⅵ) [J].中国环境科学,2022,42(2):745-752.
	ZHENG H L, ZHONG Z, ZOU H, et al.. Synthesis of magnetic cationic chitosan flocculant by low-pressure UV light for the removal of Cr (Ⅵ) [J]. China Environ. Sci., 2022, 42(2):745-752.
39	黄廷. 离子型壳聚糖基絮凝剂的合成及其混凝性能研究[D].重庆:重庆工商大学,2021.
	HUANG T. Synthesis and coagulation performance of ionic chitosan-basaed flocculants [D]. Chongqing: Chongqing Technology and Business University, 2021.
40	LIU Y Z, ZHENG H L, SUN Y J, et al.. Synthesis of novel chitosan-based flocculants with amphiphilic structure and its application in sludge dewatering: role of hydrophobic groups [J/OL]. J. Clean. Prod., 2020, 249: 119350 [2022-04-10]. .
41	陈炜,沈少航,闵广宇,等.接枝型阳离子淀粉絮凝剂在污泥脱水中的应用与机理研究[J].环境化学,2021,40(7):2217-2225.
	CHEN W, SHEN S H, MIN G Y, et al.. Application and mechanism of a graft cationic starch-based flocculant in sludge dewatering [J]. Environ. Chem., 2021, 40(7):2217-2225.
42	ZHANG L W, HUA J R, ZHU W J, et al.. Flocculation performance of hyperbranched polyethylenimine-grafted cellulose in wastewater treatment [J]. ACS Sustainable Chem. Eng., 2018, 6(2):1592-1601.
43	曹雨,田秀枝,蒋学,等.阳离子化改性纳米纤维素的合成及其脱色性能[J].东北林业大学学报,2020,48(10):104-108.
	CAO Y, TIAN X Z, JIANG X, et al.. Synthesis and decolorization properties of the cationically modified nanocrystalline cellulose flocculant [J]. J. For. Res., 2020, 48(10):104-108.
44	陈念.木质素基阳离子聚丙烯酰胺絮凝剂的制备及其在水处理中的应用[D].广州:华南理工大学,2020.
	CHEN N. Preparation of lignin-based cationic polyacrylamide flocculant and its application for water flocculation [D]. Guangzhou: South China University of Technology, 2020.

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