Journal of Agricultural Science and Technology ›› 2024, Vol. 26 ›› Issue (4): 164-173.DOI: 10.13304/j.nykjdb.2023.0490

• BIO-MANUFACTURING & RESOURCE AND ECOLOGY • Previous Articles    

Study on Resistivity Characteristics and Evaluation Model of Cadmium Contaminated Laterite

Xiaoshuang CHEN1(), Xingqian XU1(), Xi ZHAO1, Xin QU2, Haijun WANG1, Guangcan PENG1   

  1. 1.College of Water Conservancy,Yunnan Agricultural University,Kunming 650201,China
    2.School of Civil and Architecture Engineering,Anyang Institute of Technology,Henan Anyang 455000,China
  • Received:2023-06-25 Accepted:2023-12-18 Online:2024-04-15 Published:2024-04-23
  • Contact: Xingqian XU

镉污染红黏土电阻率特性及其评价模型研究

陈小双1(), 徐兴倩1(), 赵熹1, 屈新2, 王海军1, 彭光灿1   

  1. 1.云南农业大学水利学院,昆明 650201
    2.安阳工学院土木与建筑工程学院,河南 安阳 455000
  • 通讯作者: 徐兴倩
  • 作者简介:陈小双 E-mail:cxs17352480929@163.com
  • 基金资助:
    云南省基础研究计划面上基金项目(202101AT070271);国家自然科学基金项目(41867040);云南省高层次人才培养支持计划“青年拔尖人才”专项

Abstract:

To investigate the influence characteristic of cadmium on the resistivity of laterite, the laterite samples with different water content, dry density and cadmium content were tested to analyze the relationships between the influence factors and the resistivity of laterite using the two-electrode method,and finally the resistivity evaluation model of the cadmium contaminated laterite was proposed. The results showed that the resistivity of cadmium-contaminated laterite decreased with the increasing of dry density, water content and temperature. The resistivity sharply decreased in the range of dry density less than 1.30 g·cm-3, then gradually decreased and further stabilized. On the condition of different cadmium content, the resistivity gradually decreased with the increasing water content, and the most significant decrease was observed when the dry density was 1.20 g·cm-3. Under the same dry density and water content, the effect of temperature above 0 ℃ on resistivity was not significant. The increasing cadmium gave rise to the decreasing resistivity gradually, and the change in resistivity was significant when the cadmium content was less than 100 mg·kg-1. Considering the characteristics of dry density, water content and temperature comprehensively, the resistivity evaluation model of cadmium-contaminated laterite was established by the introduction of the volume water content,which had high fitting accuracy(R2=0.939 9), and the measured resistivity values were in good agreement with the model calculated resistivity values. The average mean absolute percentage error and root mean square error were 4.77% and 0.07,respectively. It could provided a theoretical model for the rapid electrical detection of heavy metal cadmium pollution in laterite areas, and it was beneficial for the quality evaluation of regional laterite cultivated land as a convenient analytical method.

Key words: laterite, cadmium pollution, impact factor, resistivity, model

摘要:

为探究重金属污染物镉对红黏土电阻率特性的影响特征,制备不同含水率、干密度、镉含量的红黏土试样,采用二极法进行电阻率测试,分析不同因素与红黏土电阻率的关系,建立镉污染红黏土电阻率评价模型。结果表明,镉污染红黏土电阻率随着干密度、含水率和温度的增加均呈下降趋势,干密度小于1.30 g·cm-3范围内电阻率急剧下降,随后电阻率逐渐减小并趋于稳定;在不同镉含量条件下随着含水率增加电阻率逐渐减小,在干密度为1.20 g·cm-3时电阻率下降最显著;在干密度、含水率相同条件下,0 ℃以上温度变化对电阻率的影响不明显,镉溶液掺入量增加导致电阻率逐渐减小,当镉含量小于100 mg·kg-1时电阻率变化幅度较大。综合考虑电阻率随干密度、含水率和温度变化特征,引入体积含水量建立镉污染红黏土电阻率评价模型,拟合精度较高(R2=0.939 9),实测值与模型值较吻合,平均绝对百分比误差和均方根误差分别为4.77%、0.07。该模型可为红黏土地区重金属镉污染度的电法快速检测提供理论模型参考,为区域性红黏土耕地质量评价提供便捷分析手段。

关键词: 红黏土, 镉污染, 影响因素, 电阻率, 模型

CLC Number: